アノマー効果

アノマー効果 — ヘテロ原子に隣接する置換基が軸位を選好する立体電子効果.

概要

en stereoelectronic effect, tendency of heteroatomic substituents adjacent to a heteroatom within a cyclohexane ring to prefer the axial orientation instead of the less hindered equatorial orientation that would be expected from steric considerations
es efecto estereolectrónico en anillos de ciclohexano con heteroátomos 機械翻訳
de Stereoelektronischer Effekt, welcher die energetische Bevorzugung bestimmter Molekülkonformationen erklärt
fr effet stéréoélectronique
pt efeito estereosseletrônico em anéis de ciclohexana com heteroátomos 機械翻訳
it effetto stereoelettronico nei carboidrati e sistemi eterociclici 機械翻訳